鲁统部
鲁统部(Lu Tongbu),男,1964年8月出生,山东省莒南县, 1993年兰州大学毕业。博士,教授,博士生导师。
基本内容
主要研究方向:
1. 大环金属配合物模拟金属酶活性中心的研究;
2. 大环桥联金属配位聚合物及高温分子磁体的研究。
工作简历:
1993~1995 中山大学化学系做博士后研究。
1995~1998 中山大学化工学院工作。
1998~1999 Texas A&M大学化学系进修。
1999~至今 中山大学化工学院工作。
讲授主要课程:
为本院和外院本科生讲设《无机化学》、《普通化学》、《无机化学实验》等多门基础课和实验课。
科研基金:
1. 广东省自然科学基金 “葡萄糖氧化酶的提纯及金属离子对其活力影响的机理研究”,已结题。
2. 广东省自然科学基金 “大环金属配合物作为金属酶模型的研究”, 在研中。
3. 国家自然科学基金 “大环配位聚合物的分子设计”,在研中。
4. 教育部资助优秀年轻教师基金 “大环类超分子化合物的自组装”, 在研中。
获奖情况:
1. 混配配合物的生物功能、作用机制及其应用探索,广东省自然科学一等奖和省高教厅科技进步一等奖,1996年。
2. 金属酶体系的结构、机制和模拟研究,教育部科技进步二等奖,1998年。
3. 生物工程方法生产葡萄糖酸锌(镁、锰、内脂)新工艺的研究,教育部科技进步二等奖,1998
主要学术论文: 1.Anion Recognition of Chloride and Bromide by a Rigid Dicobalt(II) CryptateJia-Mei Chen, Xiao-Mei Zhuang, Li-Zi Yang, Long Jiang, Xiao-Long Feng, and Tong-Bu Lu*., 2008, 47, 3158-3165.
2.Spontaneous Resolution of a Racemic Nickel(II) Complex and Helicity Induction via Hydrogen Bonding: The Effect of Chiral Building Blocks on the Helicity of 1D Chains Guang-Chuan Ou, Long Jiang, Xiao-Long Feng, and Tong-Bu Lu*., 2008, 47, 2710-2718.
3.Unusual pH value dependent encapsulation and release of water-methanol binary guests by a cryptand host Li-Zi Yang, Long Jiang, Xiao-Long Feng, and Tong-Bu Lu*, on the web.
4.Four 3D Porous Metal-Organic Frameworks with Various Layered and Pillared Motifs Wen-Guan Lu, Long Jiang, Xiao-Long Feng, and Tong-Bu Lu*Des., 2008, 8, 986-994.
5.Three Achiral and One Chiral Coordination Polymers Containing Helical Chains: The Chirality Transfer Between the Helical Chains Wen-Guang Lu, Jin-Zhong Gu, Long Jiang, Min-Yu Tan, and Tong-Bu Lu*Des., 2008, 8, 192-199.
6.A Sponge-Like 3D Porous Coordination Polymer Showing Selective Adsorption Trace Amount of Water from Organic Solvents Jin-Zhong Gu, Wen-Guan Lu, Long Jiang, Hong-Cai Zhou, and Tong-Bu Lu*., 2007, 46, 5835-5837.
7 CO2 Fixation and Transformation by a Dinuclear Copper Cryptate in an Acidic Condition Jia-Mei Chen, Wei Wei, Xiao-Long Feng, and Tong-Bu Lu* 2007, 2, 710-719.
8.Interchain Solvents Induced Chirality Change of 1D Helical Chains: From Achiral to Chiral Crystallization Long Jiang, Xiao-Long Feng, Cheng-Yong Su, Xiao-Ming Chen, and Tong-Bu Lu*., 2007, 46, 2637-2644.
9.Syntheses, Structures, and Magnetic Properties of the Face-Centered Cubic Clusters [Tp8(H2O)12M6Fe8(CN)24]4+ (M = Co, Ni) Long Jiang, Hye Jin Choi, Xiao-Long Feng, Tong-Bu Lu*, and Jeffrey R. Long*., 2007, 46, 2181-2186.
10. Synthesis, Structures and Magnetic Properties of a Series of Cyano-Bridged Fe-Mn Bimetallic Complexes Long Jiang, Xiao-Long Feng, Tong-Bu Lu,* and Song Gao*., 2006, 45, 5018-5026.
11.Formation of a Decameric Water Ring in a Cryptand-Phthalic Acid Supramolecular Adduct Yu Li, Long Jiang, Xiao-Long Feng, Tong-Bu Lu*,., 2006, 6, 1074-1077.
12. Two Stable 3D Metal-Organic Frameworks Constructed by Nanoscale Cages via Sharing the Single-Layer Walls Wen-Guan Lu, Cheng-Yong Su, Tong-Bu Lu,* Long Jiang, and Jia-Mei Chen ., 2006, 128, 34-35.
13.Three 3D Coordination Polymers Constructed by Cd(II) and Zn(II) with Imidazole-4,5-Dicarboxylate and 4,4¢-Bipyridyl Building Blocks Wen-Guan Lu, Long Jiang, Xiao-Long Feng, Tongbu Lu*., 2006, 6, 564-571.
14.Two Supramolecular Isomers of Molecular Squares and 1D Helical Chains With Alternating Right- and Left-Handed Chirality Long Jiang, Tongbu Lu*, Xiaolong Feng*., 2005, 44, 7056-7062.
15.Supramolecular Architectures of Macrocyclic Nickel(II) Complexes with Defined Structures of cis- and trans- Configurations Long Jiang, Xiaolong Feng, Tongbu Lu*., 2005, 5, 1469-1475.
16.Self-Assembly of Right-Handed Helical Infinite Chain, One- and Two-Dimensional Coordination Polymers Tuned via Anions Long Yi, Xing Yang, Tongbu Lu, Peng Cheng., 2005, 5, 1215-1219.
17.Modelling Spin Interactions in A Cyclic Trimer and A Cuboidal Co4O4 Core with Co(II) in Tetrahedral and Octahedral Environments John F. Berry, F. Albert Cotton, Chun Y. Liu, Tongbu Lu, Carlos A. Murillo, Boris S. Tsukerblat, Dino Villagrán, Xiaoping Wang., 2005, 127, 4895-4902.
18.Extended metal atom chains (EMACs) of five chromium or cobalt atoms: Symmetrical or unsymmetrical J. F. Berry, F. A. Cotton, C. S. Fewox, Tongbu Lu, C. A. Murillo, Xiaoping Wang ., Dalton Trans., 2004, 2297-2302.
19.Molecular and Electronic Structures by Design: Tuning Symmetrical and Unsymmetrical Linear Trichromium Chains J. F. Berry, F. A. Cotton, Tongbu Lu, C. A. Murillo, B. K. Roberts, Xiaoping Wang,, 2004, 126, 7082-7096.
20. C-C Bond Cleavage of Acetonitrile by a Dinuclear Copper(II) Cryptate Tongbu Lu*, Xiaomei Zhuang, Yanwu Li, Shi Chen,, 2004, 126, 4760-4761
21.Increasing solubility and stability of linear tricobalt(II) chains with depa (diethyldipyridylamide) ligands John F. Berry, F. Albert Cotton, Tongbu Lu, Carlos A. Murillo,Inorg. Chem., 2003, 42, 4425-4430.
22.Enhancing the stability of trinickel molecular wires and switches: Ni36+/7+John F. Berry, F. Albert Cotton, Tongbu Lu, Carlos A. Murillo, Xiaoping Wang,., 2003, 42, 3595-3601.
23.Additional steps toward molecular scale wires: Further study of Ni510+/11+ Chains Embraced by Polypyridylamide Ligands John F. Berry, F. Albert Cotton, Peng Lei, Tongbu Lu, Carlos A. Murillo,., 2003, 42, 3534-3539.
24.Interaction of macrocyclic copper(II) complexes with calf thymus DNA: Effects of the side chains of the ligands on the DNA-binding behaviors Jie Liu, Hao Zhang, Caihong Chen, Hong Deng, Tongbu Lu, Liangnian Ji J. Chem. Soc., Dalton Trans., 2003, 114-119.
25.DNA-binding and cleavage studies of macrocyclic copper(II) complexes Jie Liu, Tixiang Zhang, Tongbu Lu, Lianghu Qu, Hui Zhou, Qianling Zhang, Liangnian Ji,J.., 2002, 91, 269-276.
26.NiL]3[BTC]2×14H2O (L = 3,10-bis(2-ethyl)-1,3,5,8,10,12-hexaazacyclo-tetradecane, BTC = 1,3,5- benzene-tricarboxylate): synthesis, structure and unique selected guest molecule absorption properties Tongbu Lu*, Hua Xiang, Rudy L. Luck, Long Jiang, Zongwan Mao, Liangnian Ji ., 2002, 26, 969-971.
27.[NiL1]3[Cr(CN)6]2×18H2O (L1 = 3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexaaza cyclotetradecane): A two-dimensional bimetallic assembly exhibiting antiferromagnetic ordering and metamagnetic behavior Hua Xiang, Song Gao, Tongbu Lu*, Rudy L. Luck, Zongwan Mao, Xiaoming Chen, Liangnian Ji,., 2001, 25, 875-878.
28.[NiL]2[Fe(CN)6]×4H2O ( L = 3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexaaza cyclotetra-decane): A novel three dimensional iron(II)-nickel(II) cyanide bridged bimetallic assembly with a vat-like tructure Tongbu Lu*, Hua Xiang, Chengyong Su, Peng Cheng, Zongwan Mao, Liangnian Ji ,New J. Chem., 2001, 25, 216-217.
29.New Linear Tricobalt Complex of Di(2-pyridyl)amide (dpa), [Co3(dpa)4(CH3CN)2] [PF6]2R. Clérac, F. A. Cotton, K. R. Dunbar, Tongbu Lu, C. A. Murillo, Xiaoping Wang,Inorg. Chem., 2000, 39, 3065-3070.
30.A New Linear Tricobalt Compound with Di-(2-pyridyl)amide (dpa) Ligands: Structural and Magnetic Properties, Including Two-Sept Spin Crossover, of [Co3(dpa)4Cl2][BF4] R. Clerac, F. A. Cotton, K. R. Dunbar, Tongbu Lu, C. A. Murillo, Xiaoping Wang,, 2000, 122, 2272-2278.
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